If you’re looking for NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics”, then you’ve arrived at the perfect destination. Our platform offers a comprehensive collection of solutions that cover every aspect of Chemical Kinetics.
Whether you’re struggling with determining reaction orders or interpreting rate constants, our step-by-step explanations and practice questions will ensure your success. Don’t miss out on this invaluable tool for mastering Chemical Kinetics. Here’s you will get class 12 chemistry chapter 4 intext and exercises solutions in the pdf format.
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Download the PDF of NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics” Exercises
Top 10 Concepts Covered in Class 12 Chemistry Chapter 4 “Chemical Kinetics”
Here are the top 10 concepts covered in Class 12 Chemistry Chapter 4 “Chemical Kinetics”:
- Rate of Reaction: The change in concentration of reactants or products per unit time.
- Factors Affecting Reaction Rates: The influence of nature and state of reactants, concentration, temperature, and catalysts on the rate of reactions.
- Rate Law and Rate Constant: The mathematical relationship between the reaction rate and the molar concentration of reactants, and the constant of proportionality in this equation.
- Order of Reaction: The sum of the powers of the concentration terms in the rate equation.
- Molecularity of Reaction: The number of reacting species that collide simultaneously to bring about a chemical change.
- Integrated Rate Equations: Mathematical expressions that relate the concentration of reactants to time for zero, first, and second-order reactions.
- Half-Life of Reactions: The time required for the concentration of a reactant to reduce to half its initial value.
- Arrhenius Equation: The equation that shows the dependence of the rate constant on temperature and activation energy.
- Activation Energy: The minimum energy required for a reaction to occur.
- Catalysis: The process by which the rate of a chemical reaction is increased by a substance called a catalyst.

Key Formulas to Remember for NCERT Class 12 Chemistry Chapter 4 “Chemical Kinetics”
- Rate of Reaction:

Where ([A]) and ([B]) are the concentrations of the reactants and products, respectively, and (t) is time.
- Rate Law:

Where (k) is the rate constant, ([A]) and ([B]) are the concentrations of reactants, and (m) and (n) are the orders of the reaction with respect to each reactant.
- Integrated Rate Law for First Order Reactions:

Where ([A]) is the concentration of reactant at time (t), (k) is the rate constant, and ([A]_0) is the initial concentration.
- Half-Life for First Order Reactions:

Where (t_{1/2}) is the half-life of the reaction and (k) is the rate constant.
- Arrhenius Equation:

Where (k) is the rate constant, (A) is the pre-exponential factor, (E_a) is the activation energy, (R) is the gas constant, and (T) is the temperature in Kelvin.
- Second Order Reaction (for one reactant):

Where ([A]) is the concentration of reactant at time (t), (k) is the rate constant, and ([A]_0) is the initial concentration.
- Second Order Reaction (for two reactants):

Where ([A]) and ([B]) are the concentrations of the two reactants at time (t), (k) is the rate constant, and ([A]_0) and ([B]_0) are the initial concentrations.
What Are the Benefits of Using NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics”?
Here’s a list of benefits of using NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics”:
- Gain a thorough understanding of concepts with detailed explanations.
- Save time with expertly crafted solutions by subject matter experts.
- Improve problem-solving skills with various solved examples.
- Prepare effectively for board exams with tailored solutions.
- Accessible anytime online for convenient studying.
Tips for Using NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics”
Here are some tips for effectively using NCERT Solutions for Class 12 Chemistry Chapter 4 “Chemical Kinetics”:
- Start with Theory: Before attempting the problems, ensure you have a solid understanding of the theoretical concepts.
- Use Solutions as a Reference: Treat the solutions as a reference to verify your answers and understand different approaches to solving problems.
- Don’t Skip Steps: While it may be tempting to jump to the solution, try solving the problem on your own first, then check the solution.
- Identify Patterns: Look for patterns in the problems and solutions to understand common types of questions and how to approach them.
- Make Notes: Note down important formulas, concepts, and problem-solving techniques from the solutions for quick revision.
- Understand the Process: Focus on understanding the process of arriving at the solution rather than just the final answer.
- Practice Regularly: Consistent practice using the solutions can help reinforce concepts and improve problem-solving speed.
- Clarify Doubts: If you’re unsure about any part of the solution, seek clarification from teachers or peers.
- Stay Updated: Ensure you’re using the latest version of the NCERT solutions to stay in line with the current syllabus.
- Apply Knowledge: Try applying the concepts learned to solve similar problems from other sources or previous year question papers.
- For more information on NCERT, visit https://ncert.nic.in/
Common Mistakes to Avoid in NCERT Class 12 Chemistry Chapter 4 “Chemical Kinetics”
When studying NCERT Class 12 Chemistry Chapter 4 “Chemical Kinetics,” students should be mindful to avoid these common mistakes:
- Confusing Rate of Reaction with Rate Constant: Remember that the rate of reaction varies with concentration, while the rate constant does not.
- Incorrect Use of Rate Laws: Ensure you apply the correct rate law for the order of the reaction and do not confuse the overall order with the order with respect to one reactant.
- Misinterpreting Orders of Reactions: The order of a reaction is determined experimentally and not from the stoichiometry of the reaction equation.
- Overlooking Units: Always check the units when calculating rate constants, as they change with the order of the reaction.
- Neglecting Temperature’s Role: Be aware of how temperature affects reaction rates and the Arrhenius equation’s parameters.
- Mistakes in Half-Life Calculations: For first-order reactions, the half-life is constant, but for other orders, it changes with concentration.
- Misapplication of Arrhenius Equation: Understand the significance of activation energy and the pre-exponential factor when using this equation.
- Ignoring the Collision Theory: Recognize the importance of the orientation and energy of colliding particles in determining reaction rates.
- Errors in Integrated Rate Equations: Use the correct form of the integrated rate equation based on the order of the reaction.
- Assuming Instantaneous Equilibrium: In reversible reactions, equilibrium is reached over time, and the rates of the forward and reverse reactions must be considered.